Spontaneous Oligomerization of Epibromohydrine With Benzimidazole

نویسنده

  • A. I. Ismailov
چکیده

In this paper, we have synthesized oligomers of epibromohydrine (EBG) with benzimidazole (BIZ) for the first time. According to spectroscopic studies and the dependence of the reaction rate on the ratio of the starting materials, the temperature the mechanism and kinetics of the objective laws of synthesis processes were established. It was established for the first time that in the interaction of EBG with BIZ spontaneous polymerization process proceeds with the formation of soluble oligomeric products containing quaternary ammonium groups. Zwitter-ionic reaction mechanism of interaction EBG with BIZ was proposed. A series of new metal-containing oligomers based on the products of interaction EBG with BIZ with the salts of divalent metals copper and cobalt that has stabilizing properties has been synthesized and studied.

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تاریخ انتشار 2015